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If you go to Chile, you can use Cata buses http://www.catainternacional.com/prueba/index.php Just visited Mendoza and returned on one of their Royal Suite buses which was great - good food, really sweet staff, comfortable chairs, individual screens to watch the (albeit terrible) film. Highly...

Depends what you consider a good quality of life, and what that involves for you i think most young expats would be happy on that.