ajoknoblauch
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For the best wines, you should drive east until you reach a wine-producing region in Argentina.
Barring that, Montes Alpha is one of Chile's best producers, and Los Vascos is the Rothschild family's holding in Chile, also excellent.
Driving east from Talca won't get you to any Argentine wine-producing area. Driving northeast will get you to San Rafael which, though it's decent, can't match the rest of Mendoza province.